Size?Selective Photoelectrochemical Reactions in Microporous Environments: Clark Probe Investigation of Pt@g?C ₃ N ₄ Embedded into Intrinsically Microporous Polymer (PIM?1)

Nanoelectrospray aerosols from microporous polymer wick sources

A Conjugated Microporous Polymer for Palladium‐Free, Visible Light‐Promoted Photocatalytic Stille‐Type Coupling Reactions

The Stille coupling reaction is a versatile method to mainly form aromatic C-C bonds. However, up to now, the use of palladium catalysts is necessary. Here, a palladium-free and photocatalytic Stille-type coupling reaction of aryl iodides and aryl stannanes catalyzing a conjugated microporous polymer-based phototcatalyst under visible light irradiation at room temperature is reported. The novel...

Two-photon fluorescent microporous bithiophene polymer via Suzuki cross-coupling.

A microporous bithiophene polymer (MBP) stable up to 460 °C was synthesized using bithiophene and biphenyl as building blocks through Suzuki cross-coupling. The as-obtained MBP product exhibits green fluorescence peaked at 530 nm, and most interestingly, a two-photon fluorescence was observable from MBP upon excitation by an 800 nm femtosecond laser.

Microporous polymer network films covalently bound to gold electrodes.

Covalent attachment of a microporous polymer network (MPN) on a gold surface is presented. A functional bromophenyl-based self-assembled monolayer (SAM) formed on the gold surface acts as co-monomer in the polymerisation of the MPN yielding homogeneous and robust coatings. Covalent binding of the films to the electrode is confirmed by SEIRAS measurements.

Microporous sulfur-doped carbon from thienyl-based polymer network precursors.

Porous sulfur-doped carbon was synthesised by using a thienyl-based polymer network as a precursor. The sulfur amount varies from 5-23 m% while the materials show microporosity with BET surface areas of up to 711 m(2) g(-1).